What's the complete setup hardware wise? CPU, RAM, Motherboard, OS, etc... Also are you using the latest LSI driver for the controller and have the latest firmware loaded onto the controller.
How much RAM does the LSI controller have and what is the internal cache setup? Also does the controller have a battery backup unit attached, and is write caching turned on?
RAID5 will typically have slow write speeds due to parity calculations if the RAID controller has a slow CPU (or no dedicated XOR CPU), and/or it's cache profile setup is not geared for RAID5.
I would (based on the info given):
1. Check that the cached writes is turned ON in the controllers BIOS.
2. See if you set the percentage of cache more geared for writes than reads. (Some BIOSes don't have this option). It's been a while since I've used LSI controllers.
3. Switch to RAID 10, and see if this improves your overall performance.
4. Update to Windows 7...