"Owing to technical limitations, the size of a single volume is limited to 16, 108, or 200 terabytes (TB) on certain Synology NAS models1.
...
Note:
For more information on the limitation of each Synology NAS model, please refer to the items of Maximum Single Volume Size and Maximum Internal Volume Number in its specifications. Some models with expandable RAM can be upgraded to 32GB or higher to support a single volume size of 200TB on RAID 5 or RAID 6 groups. Please refer to your model’s datasheet for more information."
https://www.synology.com/en-us/know...logy_NAS_have_a_single_volume_size_limitation
Looks like you would want to double check the specific model you are looking at.